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You can review the component pieces here. If you enable all four, you'll start the game kind of armed to the teeth, with some gear that sells for a rather large sum of caps - if that's what you're into, by all means, turn all four on. All they do is add some starting equipment. The Courier's Stash consists of 4 DLC add ons that each comprise one of the preorder bonuses the game came with from different retailers. So, let's start with the easy ones, the 4 Courier's Stash packs, and the Gun Runners Arsenal.
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